/ Home
/ SUBMISSION

/ The BJOC
/ Diamond Open Access
/ Journal Statistics
/ Editorial Board
/ Community
/ Call for papers

/ Latest Articles
/ Most accessed
/ Thematic issues
/ Volumes
/ Authors

/ Alerts

/ TWITTER
/ LINKEDIN
/ Mastodon
/ RSS FEED

Empty search

Article Type

Publication Date Range

Search Tips

This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.

Search Examples

aromatic	the word “aromatic”
aromatic aldehyde	the word “aromatic” OR “aldehyde”
+aromatic +aldehyde	both words “aromatic” AND “aldehyde”
+aromatic -aldehyde	the word “aromatic” but NOT “aldehyde”
“aromatic aldehyde”	the exact phrase “aromatic aldehyde”
benz*	words which begin with “benz”, such as “benzene” or “benzyl”
benz*yl	words that begin with “benz” and end with “yl”, such as “benzyl” or “benzoyl”
benzyl~	words that are close to the word “benzyl”, such as “benzoyl” (i.e., fuzzy search)

BROWSE
Latest Articles
Most accessed
thematic issues
volumes
authors

BROWSE

Latest Articles Most Accessed Thematic Issues Volumes Authors

Author

2 article(s) from Gladysz, John A

Non-metal-templated approaches to bis(borane) derivatives of macrocyclic dibridgehead diphosphines via alkene metathesis

Tobias Fiedler,
Michał Barbasiewicz,
Michael Stollenz and
John A. Gladysz

Beilstein J. Org. Chem. 2018, 14, 2354–2365, doi:10.3762/bjoc.14.211

PDF

Graphical Abstract

Scheme 1: Syntheses of gyroscope like platinum and rhodium complexes and dibridgehead diphosphines derived th...

Jump to Scheme 1

Scheme 2: Synthesis and alkene metathesis of the monophosphorus precursor 1·BH₃.

Jump to Scheme 2

Figure 1: The ¹³C{¹H} NMR spectra (CDCl₃, 100 MHz) of in,out-2·2BH₃, (in,in/out,out)-2·2BH₃, 6·2BH₃, and the ...

Jump to Figure 1

Scheme 3: Synthesis of the diphosphorus precursor 11·2BH₃.

Jump to Scheme 3

Scheme 4: Truncated approaches to the diphosphorus precursor 11·2BH₃ from 10.

Jump to Scheme 4

Scheme 5: Alkene metathesis of the diphosphorus precursor 11·2BH₃.

Jump to Scheme 5

Scheme 6: Schematic comparison of the key alkene metathesis steps in Scheme 2 and Scheme 5.

Jump to Scheme 6

Scheme 7: Steps that set the in,in/out,out vs in,out stereochemistry of 2·2BH₃ in Scheme 2 and Scheme 5.

Jump to Scheme 7

Scheme 8: Another non-metal-templated approach to dibridgehead diphosphorus compounds.

Jump to Scheme 8

Scheme 9: Previously synthesized dibridgehead diphosphine diboranes.

Jump to Scheme 9

Scheme 10: Alkene metathesis of the tetraalkenyldiphosphine diborane 19·2BH₃.

Jump to Scheme 10

Album

Supp Info

Full Research Paper

Published 07 Sep 2018

Full text

Syntheses, structures, and stabilities of aliphatic and aromatic fluorous iodine(I) and iodine(III) compounds: the role of iodine Lewis basicity

Tathagata Mukherjee,
Soumik Biswas,
Andreas Ehnbom,
Subrata K. Ghosh,
Ibrahim El-Zoghbi,
Nattamai Bhuvanesh,
Hassan S. Bazzi and
John A. Gladysz

Beilstein J. Org. Chem. 2017, 13, 2486–2501, doi:10.3762/bjoc.13.246

PDF

Graphical Abstract

Scheme 1: Some previously reported iodine(III) dichlorides relevant to this work.

Jump to Scheme 1

Scheme 2: Syntheses of fluorous compounds of the formula R_f_nCH₂X.

Jump to Scheme 2

Scheme 3: Syntheses of fluorous compounds of the formula CF₃CF₂CF₂O(CF(CF₃)CF₂O)_xCF(CF₃)CH₂X'.

Jump to Scheme 3

Scheme 4: Attempted syntheses of aliphatic fluorous iodine(III) dichlorides R_f_nICl₂.

Jump to Scheme 4

Scheme 5: Syntheses of aromatic fluorous compounds with one perfluoroalkyl group.

Jump to Scheme 5

Scheme 6: Syntheses of aromatic fluorous compounds with two perfluoroalkyl groups.

Jump to Scheme 6

Figure 1: Partial ¹H NMR spectra (sp² CH, 500 MHz, CDCl₃) relating to the reaction of 1,3,5-(R_f6)₂C₆H₃I and Cl...

Jump to Figure 1

Figure 2: Two views of the molecular structure of 1,3,5-(R_f6)₂C₆H₃I with thermal ellipsoids at the 50% probab...

Jump to Figure 2

Figure 3: Ball-and-stick and space filling representations of the unit cell of 1,3,5-(R_f6)₂C₆H₃I.

Jump to Figure 3

Figure 4: Free energies of chlorination of relevant aryl and alkyl iodides to the corresponding iodine(III) d...

Jump to Figure 4

Scheme 7: Other relevant fluorous compounds and reactions.

Jump to Scheme 7

Figure 5: Views of the helical motif of the perfluorohexyl segments in crystalline 1,3,5-(R_f6)₂C₆H₃I (left) a...

Jump to Figure 5

Album

Supp Info

Full Research Paper

Published 23 Nov 2017

Full text

Other Beilstein-Institut Open Science Activities

/ Help / Support & Contact / Alerts / Privacy Policy / Terms & Conditions / Impressum